Volcanic Islands

COMPARISON OF THE OBSIDIAN BEDS AND ALTERNATING STRATA OF ASCENSION, WITH THOSE OF OTHER COUNTRIES.

I have been struck with much surprise, how closely the excellent description of the obsidian rocks of Hungary, given by Beudant ("Voyage en Hongrie" tome 1 page 330; tome 2 pages 221 and 315; tome 3 pages 369, 371, 377, 381.), and that by Humboldt, of the same formation in Mexico and Peru ("Essai Geognostique" pages 176, 326, 328.), and likewise the descriptions given by several authors (P. Scrope "Geological Transactions" volume 2 second series page 195. Consult also Dolomieu "Voyage aux Isles Lipari" and D'Aubuisson "Traite de Geogn." tome 2 page 534.) of the trachytic regions in the Italian islands, agree with my observations at Ascension. Many passages might have been transferred without alteration from the works of the above authors, and would have been applicable to this island. They all agree in the laminated and stratified character of the whole series; and Humboldt speaks of some of the beds of obsidian being ribboned like jasper. (In Mr. Stokes' fine collection of obsidians from Mexico, I observe that the sphaerulites are generally much larger than those of Ascension; they are generally white, opaque, and are united into distinct layers: there are many singular varieties, different from any at Ascension. The obsidians are finely zoned, in quite straight or curved lines, with exceedingly slight differences of tint, of cellularity, and of more or less perfect degrees of glassiness. Tracing some of the less perfectly glassy zones, they are seen to become studded with minute white sphaerulites, which become more and more numerous, until at last they unite and form a distinct layer: on the other hand, at Ascension, only the brown sphaerulites unite and form layers; the white ones always being irregularly disseminated. Some specimens at the Geological Society, said to belong to an obsidian formation from Mexico, have an earthy fracture, and are divided in the finest parallel laminae, by specks of a black mineral, like the augitic or hornblendic specks in the rocks at Ascension.) They all agree in the nodular or concretionary character of the obsidian, and of the passage of these nodules into layers. They all refer to the repeated alterations, often in undulatory planes, of glassy, pearly, stony, and crystalline layers: the crystalline layers, however, seem to be much more perfectly developed at Ascension, than in the above-named countries. Humboldt compares some of the stony beds, when viewed from a distance, to strata of a schistose sandstone. Sphaerulites are described as occurring abundantly in all cases; and they everywhere seem to mark the passage, from the perfectly glassy to the stony and crystalline beds. Beudant's account (Beudant "Voyage" tome 3 page 373.) of his "perlite lithoide globulaire" in every, even the most trifling particular, might have been written for the little brown sphaerulitic globules of the rocks of Ascension.

From the close similarity in so many respects, between the obsidian formations of Hungary, Mexico, Peru, and of some of the Italian islands, with that of Ascension, I can hardly doubt that in all these cases, the obsidian and the sphaerulites owe their origin to a concretionary aggregation of the silica, and of some of the other constituent elements, taking place whilst the liquified mass cooled at a certain required rate. It is, however, well-known, that in several places, obsidian has flowed in streams like lava; for instance, at Teneriffe, at the Lipari Islands, and at Iceland. (For Teneriffe see von Buch "Descript. des Isles Canaries" pages 184 and 190; for the Lipari Islands see Dolomieu "Voyage" page 34; for Iceland see Mackenzie "Travels" page 369.) In these cases, the superficial parts are the most perfectly glassy, the obsidian passing at the depth of a few feet into an opaque stone. In an analysis by Vauquelin of a specimen of obsidian from Hecla, which probably flowed as lava, the proportion of silica is nearly the same as in the nodular or concretionary obsidian from Mexico. It would be interesting to ascertain, whether the opaque interior portions and the superficial glassy coating contained the same proportional constituent parts: we know from M. Dufrenoy ("Memoires pour servir a une Descript. Geolog. de la France" tome 4 page 371.) that the exterior and interior parts of the same stream of lava sometimes differ considerably in their composition. Even should the whole body of the stream of obsidian turn out to be similarly composed with nodular obsidian, it would only be necessary, in accordance with the foregoing facts, to suppose that lava in these instances had been erupted with its ingredients mixed in the same proportion, as in the concretionary obsidian.

LAMINATION OF VOLCANIC ROCKS OF THE TRACHYTIC SERIES.

We have seen that, in several and widely distant countries, the strata alternating with beds of obsidian, are highly laminated. The nodules, also, both large and small, of the obsidian, are zoned with different shades of colour; and I have seen a specimen from Mexico in Mr. Stokes' collection, with its external surface weathered (MacCulloch states "Classification of Rocks" page 531 that the exposed surfaces of the pitchstone dikes in Arran are furrowed "with undulating lines, resembling certain varieties of marbled paper, and which evidently result from some corresponding difference of laminar structure.") into ridges and furrows, corresponding with the zones of different degrees of glassiness: Humboldt ("Personal Narrative" volume 1 page 222.), moreover, found on the Peak of Teneriffe, a stream of obsidian divided by very thin, alternating, layers of pumice. Many other lavas of the feldspathic series are laminated; thus, masses of common trachyte at Ascension are divided by fine earthy lines, along which the rock splits, separating thin layers of slightly different shades of colour; the greater number, also, of the embedded crystals of glassy feldspar are placed lengthways in the same direction. Mr. P. Scrope ("Geological Transactions" volume 2 second series page 195.) has described a remarkable columnar trachyte in the Panza Islands, which seems to have been injected into an overlying mass of trachytic conglomerate: it is striped with zones, often of extreme tenuity, of different textures and colours; the harder and darker zones appearing to contain a larger proportion of silica. In another part of the island, there are layers of pearlstone and pitchstone, which in many respects resemble those of Ascension. The zones in the columnar trachyte are generally contorted; they extend uninterruptedly for a great length in a vertical direction, and apparently parallel to the walls of the dike-like mass. Von Buch ("Description des Iles Canaries" page 184.) has described at Teneriffe, a stream of lava containing innumerable thin, plate-like crystals of feldspar, which are arranged like white threads, one behind the other, and which mostly follow the same direction. Dolomieu ("Voyage aux Isles de Lipari" pages 35 and 85.) also states, that the grey lavas of the modern cone of Vulcano, which have a vitreous texture, are streaked with parallel white lines: he further describes a solid pumice-stone which possesses a fissile structure, like that of certain micaceous schists. Phonolite, which I may observe is often, if not always, an injected rock, also, often has a fissile structure; this is generally due to the parallel position of the embedded crystals of feldspar, but sometimes, as at Fernando Noronha, seems to be nearly independent of their presence. (In this case, and in that of the fissile pumice-stone, the structure is very different from that in the foregoing cases, where the laminae consist of alternate layers of different composition or texture. In some sedimentary formations, however, which apparently are homogeneous and fissile, as in glossy clay-slate, there is reason to believe, according to D'Aubuisson, that the laminae are really due to excessively thin, alternating, layers of mica.) From these facts we see, that various rocks of the feldspathic series have either a laminated or fissile structure, and that it occurs both in masses which have injected into overlying strata, and in others which have flowed as streams of lava.

The laminae of the beds, alternating with the obsidian at Ascension, dip at a high angle under the mountain, at the base of which they are situated; and they do not appear as if they had been inclined by violence. A high inclination is common to these beds in Mexico, Peru, and in some of the Italian islands (See Phillips "Mineralogy" for the Italian Islands page 136. For Mexico and Peru see Humboldt "Essai Geognostique." Mr. Edwards also describes the high inclination of the obsidian rocks of the Cerro del Navaja in Mexico in the "Proc. of the Geolog. Soc." June 1838.): on the other hand, in Hungary, the layers are horizontal; the laminae, also, of some of the lava-streams above referred to, as far as I can understand the descriptions given of them, appear to be highly inclined or vertical. I doubt whether in any of these cases, the laminae have been tilted into their present position; and in some instances, as in that of the trachyte described by Mr. Scrope, it is almost certain that they have been originally formed with a high inclination. In many of these cases, there is evidence that the mass of liquified rock has moved in the direction of the laminae. At Ascension, many of the air-cells have a drawn out appearance, and are crossed by coarse semi-glassy fibres, in the direction of the laminae; and some of the layers, separating the sphaerulitic globules, have a scored appearance, as if produced by the grating of the globules. I have seen a specimen of zoned obsidian from Mexico, in Mr. Stokes' collection, with the surfaces of the best-defined layers streaked or furrowed with parallel lines; and these lines or streaks precisely resembled those, produced on the surface of a mass of artificial glass by its having been poured out of a vessel. Humboldt, also, has described little cavities, which he compares to the tails of comets, behind sphaerulites in laminated obsidian rocks from Mexico, and Mr. Scrope has described other cavities behind fragments embedded in his laminated trachyte, and which he supposes to have been produced during the movement of the mass. ("Geological Transactions" volume 2 second series page 200 etc. These embedded fragments, in some instances, consist of the laminated trachyte broken off and "enveloped in those parts, which still remained liquid." Beudant, also, frequently refers in his great work on "Hungary" tome 3 page 386, to trachytic rocks, irregularly spotted with fragments of the same varieties, which in other parts form the parallel ribbons. In these cases, we must suppose, that after part of the molten mass had assumed a laminated structure, a fresh irruption of lava broke up the mass, and involved fragments, and that subsequently the whole became relaminated.) From such facts, most authors have attributed the lamination of these volcanic rocks to their movement whilst liquified. Although it is easy to perceive, why each separate air-cell, or each fibre in pumice-stone (Dolomieu "Voyage" page 64.), should be drawn out in the direction of the moving mass; it is by no means at first obvious why such air-cells and fibres should be arranged by the movement, in the same planes, in laminae absolutely straight and parallel to each other, and often of extreme tenuity; and still less obvious is it, why such layers should come to be of slightly different composition and of different textures.

In endeavouring to make out the cause of the lamination of these igneous feldspathic rocks, let us return to the facts so minutely described at Ascension. We there see, that some of the thinnest layers are chiefly formed by numerous, exceedingly minute, though perfect, crystals of different minerals; that other layers are formed by the union of different kinds of concretionary globules, and that the layers thus formed, often cannot be distinguished from the ordinary feldspathic and pitchstone layers, composing a large portion of the entire mass. The fibrous radiating structure of the sphaerulites seems, judging from many analogous cases, to connect the concretionary and crystalline forces: the separate crystals, also, of feldspar all lie in the same parallel planes. (The formation, indeed, of a large crystal of any mineral in a rock of mixed composition implies an aggregation of the requisite atoms, allied to concretionary action. The cause of the crystals of feldspar in these rocks of Ascension, being all placed lengthways, is probably the same with that which elongates and flattens all the brown sphaerulitic globules (which behave like feldspar under the blowpipe) in this same direction.) These allied forces, therefore, have played an important part in the lamination of the mass, but they cannot be considered the primary force; for the several kinds of nodules, both the smallest and largest, are internally zoned with excessively fine shades of colour, parallel to the lamination of the whole; and many of them are, also, externally marked in the same direction with parallel ridges and furrows, which have not been produced by weathering.

Some of the finest streaks of colour in the stony layers, alternating with the obsidian, can be distinctly seen to be due to an incipient crystallisation of the constituent minerals. The extent to which the minerals have crystallised can, also, be distinctly seen to be connected with the greater or less size, and with the number, of the minute, flattened, crenulated air-cavities or fissures. Numerous facts, as in the case of geodes, and of cavities in silicified wood, in primary rocks, and in veins, show that crystallisation is much favoured by space. Hence, I conclude, that, if in a mass of cooling volcanic rock, any cause produced in parallel planes a number of minute fissures or zones of less tension (which from the pent-up vapours would often be expanded into crenulated air-cavities), the crystallisation of the constituent parts, and probably the formation of concretions, would be superinduced or much favoured in such planes; and thus, a laminated structure of the kind we are here considering would be generated.

That some cause does produce parallel zones of less tension in volcanic rocks, during their consolidation, we must admit in the case of the thin alternate layers of obsidian and pumice described by Humboldt, and of the small, flattened, crenulated air-cells in the laminated rocks of Ascension; for on no other principle can we conceive why the confined vapours should through their expansion form air-cells or fibres in separate, parallel planes, instead of irregularly throughout the mass. In Mr. Stokes' collection, I have seen a beautiful example of this structure, in a specimen of obsidian from Mexico, which is shaded and zoned, like the finest agate, with numerous, straight, parallel layers, more or less opaque and white, or almost perfectly glassy; the degree of opacity and glassiness depending on the number of microscopically minute, flattened air-cells; in this case, it is scarcely possible to doubt but that the mass, to which the fragment belonged, must have been subjected to some, probably prolonged, action, causing the tension slightly to vary in the successive planes.

Several causes appear capable of producing zones of different tension, in masses semi-liquified by heat. In a fragment of devitrified glass, I have observed layers of sphaerulites which appeared, from the manner in which they were abruptly bent, to have been produced by the simple contraction of the mass in the vessel, in which it cooled. In certain dikes on Mount Etna, described by M. Elie de Beaumont ("Mem. pour servir" etc. tome 4 page 131.), as bordered by alternating bands of scoriaceous and compact rock, one is led to suppose that the stretching movement of the surrounding strata, which originally produced the fissures, continued whilst the injected rock remained fluid. Guided, however, by Professor Forbes' ("Edinburgh New Phil. Journal" 1842 page 350.) clear description of the zoned structure of glacier-ice, far the most probable explanation of the laminated structure of these feldspathic rocks appears to be, that they have been stretched whilst slowly flowing onwards in a pasty condition (I presume that this is nearly the same explanation which Mr. Scrope had in his mind, when he speaks ("Geolog. Transact." volume 2 second series page 228) of the ribboned structure of his trachytic rocks, having arisen, from "a linear extension of the mass, while in a state of imperfect liquidity, coupled with a concretionary process."), in precisely the same manner as Professor Forbes believes, that the ice of moving glaciers is stretched and fissured. In both cases, the zones may be compared to those in the finest agates; in both, they extend in the direction in which the mass has flowed, and those exposed on the surface are generally vertical: in the ice, the porous laminae are rendered distinct by the subsequent congelation of infiltrated water, in the stony feldspathic lavas, by subsequent crystalline and concretionary action. The fragment of glassy obsidian in Mr. Stokes' collection, which is zoned with minute air-cells must strikingly resemble, judging from Professor Forbes' descriptions, a fragment of the zoned ice; and if the rate of cooling and nature of the mass had been favourable to its crystallisation or to concretionary action, we should here have had the finest parallel zones of different composition and texture. In glaciers, the lines of porous ice and of minute crevices seem to be due to an incipient stretching, caused by the central parts of the frozen stream moving faster than the sides and bottom, which are retarded by friction: hence in glaciers of certain forms and towards the lower end of most glaciers, the zones become horizontal. May we venture to suppose that in the feldspathic lavas with horizontal laminae, we see an analogous case? All geologists, who have examined trachytic regions, have come to the conclusion, that the lavas of this series have possessed an exceedingly imperfect fluidity; and as it is evident that only matter thus characterised would be subject to become fissured and to be formed into zones of different tensions, in the manner here supposed, we probably see the reason why augitic lavas, which appear generally to have possessed a high degree of fluidity, are not, like the feldspathic lavas, divided into laminae of different composition and texture. (Basaltic lavas, and many other rocks, are not unfrequently divided into thick laminae or plates, of the same composition, which are either straight or curved; these being crossed by vertical lines of fissure, sometimes become united into columns. This structure seems related, in its origin, to that by which many rocks, both igneous and sedimentary, become traversed by parallel systems of fissures.) Moreover, in the augitic series, there never appears to be any tendency to concretionary action, which we have seen plays an important part in the lamination of rocks, of the trachytic series, or at least in rendering that structure apparent.

Whatever may be thought of the explanation here advanced of the laminated structure of the rocks of the trachytic series, I venture to call the attention of geologists to the simple fact, that in a body of rock at Ascension, undoubtedly of volcanic origin, layers often of extreme tenuity, quite straight, and parallel to each other, have been produced; – some composed of distinct crystals of quartz and diopside, mingled with amorphous augitic specks and granular feldspar, – others entirely composed of these black augitic specks, with granules of oxide of iron, – and lastly, others formed of crystalline feldspar, in a more or less perfect state of purity, together with numerous crystals of feldspar, placed lengthways. At this island, there is reason to believe, and in some analogous cases, it is certainly known, that the laminae have originally been formed with their present high inclination. Facts of this nature are manifestly of importance, with relation to the structural origin of that grand series of plutonic rocks, which like the volcanic have undergone the action of heat, and which consist of alternate layers of quartz, feldspar, mica and other minerals.